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WBCS Preliminary Examination 2021 — General Studies · Question 43 of 200

Q43
General SciencePhysics
Pure silicon at 0 K is
  1. a.semiconductor
  2. b.metal
  3. c.insulator
  4. d.superconductor

Answer: (C) insulator

In a pure (intrinsic) semiconductor at absolute zero ($0\,K$) the valence band is completely filled and the conduction band completely empty; with no thermal energy to lift electrons across the band gap (about $1.1\,eV$ for silicon) there are no free charge carriers, so it behaves as a perfect insulator. It starts conducting only as the temperature rises - the conductivity of a semiconductor increases with temperature, the opposite of a metal. A superconductor, by contrast, loses all resistance below a critical temperature (mercury at $4.2\,K$).